Membrane Science and Technology

Position：Home >> Abstract

Preparation and performance of novel thermally stable composite reverse osmosis membranes

Authors： HU Lijie¹, ZHANG Shouhai^1,4*,GUAN Shanshan¹, JIAN ^{Xigao1,2,3,4*}

Units： 1. School of Chemical Engineering, Dalian University of Technology; 2. Institute of Polym.Sci. & Materials Dalian University of Technology; 3.Liaoning High Performance Polymer Engineering Research Center; 4. Liaoning Key Laboratory of Polymer Science and Engineering, Dalian 116024

KeyWords： poly (phthalazione ether nitrile ketone); interfacial polymerization; composite reverse osmosis membrane; thermal stability

ClassificationCode：TQ028. 8

year,volume(issue):pagination： 2013, 33(3):23-27

Abstract：

Novel thermally stable aromatic polyamide (APA) composite reverse osmosis (RO) membranes were prepared from metaphenylene diamine and trimesoyl chloride on poly (phthalazione ether nitrile ketone) (PPENK) ultrafiltration membranes by interfacial polymerization. The effects of monomers concentration and reaction time on the performance of composite membranes were studied. Furthermore, the surface morphology and chemical structure of membranes were examined by scanning electronic microscopy and fourier transform infrared spectroscopy (FT-IR), respectively. Moreover, the thermal stability of RO membranes was also discussed. When the operation temperature increased from 20 ℃ to 95 ℃, the salt rejection of membranes was kept about 97.9%, while the flux of membranes increased from 7.4 L/m2h to 31.4 L/m2h; the flux increased first then reached a plateau and the salt rejection kept constant when RO membranes in boiling water were boiled to 3 h. In a word, APA-PPENK composite RO membranes show good thermal stability.

Funds：

AuthorIntro：

胡利杰（1985-）女，河南省新乡市人，博士生，大连理工大学化工学院，从事耐高温液体分离膜的研究，hlj19851014@yahoo.com.cn. 通讯联系人，E-mail: jian4616@dl.cn，zhangshh@dlut.edu.cn.

Reference：

[1] 王晓伟，贾铭椿，杨开．反渗透膜对水中硼酸脱除性能的实验研究[J]．膜科学与技术，　2011，31(6): 78－81．
[2] 张守海，蹇锡高，杨大令．新型耐高温分离膜用高分子材料[J]．现代化工，2002， 22 (S1)：203－205．
[3] 陈连周，蹇锡高，高峡，等．新型聚芳醚酮腈的合成及表征[J]．河北工业大学学报，1999，28(5)：22－25．
[4] 蹇锡高，李琦，王明晶，等．含二氮杂萘酮联苯结构聚芳醚腈酮及其制备法[P]，中国专利，03111540．3（2004）．
[5] 周红欣．杂萘联苯聚醚酮类树脂低成本合成及性能研究[D]．大连理工大学，2011，85－89．
[6] 王国庆，蹇锡高，张守海，等．低截留分子质量新型聚芳醚腈酮超滤膜的研制[J]．现代化工，2003， 23(7)：37－40.
[7] 陈尧，陈国华，陈容，等．戊二醛- 硫酸混合交联壳聚糖/聚砜复合纳滤膜的结构与性能[J]．膜科学与技术，2007，27(4)：31－36.
[8] 邹凯伦，王丽红，张林，等．TMC/TMPIP纳滤超薄复合膜的制备[J]．化工学报，2012，63(3)：948－954．
[9] 邱实，吴礼光，张林，等．界面聚合工艺条件对反渗透复合膜性能的影响[J]．化工学报，2008，59(8)：2027－2034．
[10] 高学理，王伟伟，陈晓琳，等．界面聚合法制备海藻酸钠/聚砜复合纳滤膜[J]．膜
科学与技术，2011，31(4)：27－30．
[11] Chai G Y，Krantz W B．Formation and characterization of polyamide membranes via interfacial polymerization[J]．J Membr Sci，1994，93：175－192．
[12] 宋玉军，程淑英，刘福安，等．制NF－TFC膜的界面聚合反应研究[J]．水处理技术，2000，26(4)：203－206．
[13] Wei J，Jian X，Wu C，etal. Influence of polymer structure on thermal stability
of composite membranes[J]. J Membr Sci，2005，256：116－121．
[14] 张守海．杂环联苯聚芳醚的化学改性及其分离膜的研制[D]．大连理工大学，2002，92

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com