Membrane Science and Technology

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Impact of membrane processing conditions on PVC / SPES blend membrane performance

Authors： ZHOU Hongzhong, WU Jun, WANG Jun

Units： College of? Environmental Science and Engineering，State Environmental Protection Engineering Center for Pollution Treatment and Control in Textile Industry，Donghua University，Shanghai 201620，China

KeyWords： sulfonated polyethersulfone (SPES); polyvinyl chloride(PVC); blend membrane; antifouling

ClassificationCode：TQ325.8

year,volume(issue):pagination： 2015, 35(3):21-30

Abstract：

In this paper, after blending Polyvinyl chloride(PVC) and sulfonated polyethersulfone (SPES) together, PVC/SPES bland membranes were prepared using phase inversion method under different membrane processing conditions (polymer content of the casting solution, the temperature of the casting solution, the temperature of the gel bath and the gel bath composition), and then the pure water flux, rejection rate, tensile strength, fouling resistance and scanning electron microscope(SEM) of blend membranes were tested that in order to investigate the influence of bland membranes processing conditions on PVC / SPES blend membranes microstructure and performance. By composing the pure water flux, rejection rate, tensile strength and fouling resistance of different blend membranes, then obtained PVC / SPES blend membranes optimum conditions: the optimum polymer content of the casting solution is 16%, the temperature of the casting solution is 70 ℃, the temperature of the bath gel is 20℃, the gel bath is pour water.

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AuthorIntro：

周红中（1990-）,女,浙江淳安,硕士研究生,研究方向为膜分离技术,E-mail:hongzhong119@126.com

Reference：

[1] 周盾自,贾德民. PVC膜改性研究进展[J].合成树脂及塑料, 2005, 22 (4) :67~70.
[2] Hirose S, Shimizu A, Nose T. Preparation and structures of the poly (vinyl chloride) porous membranes[J]. Journal of Applied Polymer Science, 1979, 23(11):3193~3204.
[3] Hirose S, Yasukawa E, Nose T. Wet poly (vinyl chloride) membrane[J]. Journal of Applied Polymer Science, 1981, 26(3):1039~1048.
[4] Moody G J, Thomas J D R. Behaviour of polymer (poly (vinyl chloride)) membrane systems[J]. Journal of Power Sources, 1983, 9(2):137~146.
[5] Kajiyama T, Washizu S, Takayanagi M. Membrane structure and permeation properties of poly (vinyl 8chloride)/liquid crystal composite membrane[J]. Journal of applied polymer science, 1984, 29(12): 955~3964.
[6] Okuno H, Renzo K, Uragami T. Influence of casting solution additive, degree of polymerization, and polymer concentration on poly (vinyl chloride) membrane properties and performance[J]. Journal of membrane science, 1993, 83(2):199~209.
[7] 张召才,郭春刚,李晓明, 等. PVDF/DBP/DOP/TiO2体系流变性能研究[J]. 塑料科技, 2012, 40(2):36~40.
[8] 谭翎燕,刘金盾,张浩勤, 等. 磺化聚醚砜(SPES)/聚砜(PSF)共混超滤膜的研制[J]. 化工进展, 2007, 06:864~868.
[9] Rahimpour, A, et al. Structural and performance properties of UV-assisted TiO2 deposited nano-composite PVDF/SPES membranes[J]. Desalination, 2012, 285: 31~38.
[10] 张立忠,杨力芳,王海涛, 等. 聚醚砜/磺化聚醚砜共混膜的亲水性和血液相容性[J]. 高分子材料科学与工程, 2010, 02:40~43.
[11] 孙中华,陈夫山. DMAc/LiCl体系下纤维素/聚醚砜共混膜的制备与表征[J]. 包装工程, 2013, 05:34-36.
[12] 赵津礼,张玉忠,林立刚, 等. 新型聚醚砜/磺化聚醚砜共混超滤膜的制备及性能[J]. 天津工业大学学报, 2013, 03:1~7.
[13] 马冯,张玉忠,丁晓莉, 等. 磺化聚砜/聚醚砜共混非对称纳滤膜的制备与性能表征[J]. 膜科学与技术, 2012, 01:46~50.
[14] 高春梅,孟彦宾,奚旦立. PVDF/PVC膜化学稳定性研究[J]. 纺织学报, 2008,01:17~21.
[15] 朱士龙,张俊生,李勇,等. 制膜条件对聚偏氟乙烯/酚酞型聚醚砜共混膜性质的影响[J].吉首大学学报（自然科学版）, 2010(4):98~102.
[16] 潘春红,王磊,孟晓荣, 等. 凝胶浴条件对PVDF/CaCO3共混中空纤维膜性能和结构的影响[J]. 水处理技术. 2012(10), 38~41.
[17] 沈江南,蒋婷婷,陈永盛. 制膜条件对PVDF疏水微孔膜结构和性能的影响[J]. 浙江工业大学学报. 2011(6):591~595.
[18] 原魏,王磊,王旭东, 等. 凝胶成分对PVDF/PVP中空纤维超滤膜结构与性能的影响[J]. 水处理技术. 2011(12): 54~58.
[19] 李振雷,张玉忠, 等. 凝固浴条件对聚醚砜膜结构与渗透性能的影响[J]. 天津工业大学学报. 2008(4):12~15.
[20] 王贵恒. 高分子材料成型加工原理[M]. 北京:化学工业出版社, 1982. 279~281.
[21] 石卿. 超滤膜的仿生构建及抗污染机理的分子水平探索[D]. 天津大学博士论文, 2010年.
[22] 王艳强. 表面偏析超滤膜的制备及其抗污染机理的研究[D]. 天津大学博士论文, 2006年.
[23] 严丽,王军. PVB/PVDF共混膜性能的影响因素[J]. 化工进展, 2011,S2:282~287.
[24] Huang, J Y, et al. Surface modification of polyethersulfone membranes by blending triblock copolymers of methoxyl poly(ethylene glycol)-polyurethane-methoxyl poly(ethylene glycol)[J]. Colloids and Surfaces B-Biointerfaces, 2011. 88(1): 315~324.
[25] 丁马太,何旭敏,丁俊琪, 等. 聚氯乙烯/聚丙烯腈共混超滤膜的研究III:制膜工艺条件对共混超滤膜结构与性能的影响[J]. 水处理技术, 1992, 18(3):155~161.

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