Position:Home >> Abstract

Research on Preparation of Conductive Forward Osmosis Membrane via embedding Carbon Nanotubes Layer and Its Mitigation of Organic Fouling
Authors: XU Mengsi, MA Guangxiang, YI Xiawen, MA Tao, WANG Xinhua
Units: 1. School of Environmental and Civil Engineering, Jiangnan University, Wuxi 214122; 2. Shandong Academy of Environmental Science Co. LTD., Jinan 250100; 3. Jiangsu Engineering Laboratory for Biomass Energy and Carbon Reduction Technology, Wuxi 214122; 4. Jiangsu Cooperative Innovation Center of Technology and Material of Water Treatment, Suzhou 215009
KeyWords: forward osmosis membrane; carbon nanotube; conductive membrane; electric field; organic fouling
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2021, 41(3):9-15

Abstract:

  In order to mitigate organic fouling of forward osmosis (FO) membrane, a conductive composite forward osmosis (TFC-FO) membrane was firstly prepared in this paper via embedding an intermediate layer of carbon nanotubes (CNTs) between the porous polyethersulfone (PES) carrier and the polyamide (PA) active layer, and then its feasibility of alleviating organic fouling under the applied electric field was investigated. The results indicated that after adding the CNTs intermediate layer, compared with the conventional TFC-FO membrane, the surface roughness of the conductive TFC-FO membrane increased (46.85±6.55 nm VS 33.85±4.05 nm), and its surface resistance was greatly reduced (2.1×1012 Ω VS 54.7 Ω). In addition, the water flux of the conductive TFC-FO membrane was increased by 2.33 times, and its Js/ Jw value was reduced by about 4.72 times. During the fouling experiment without the electric field, although the flux decline of the conductive TFC-FO membrane decreased 1.9% compared with the conventional TFC-FO membrane, there was no difference in the quantity of the organic foulants. However, when applying a 2 V electric field, the flux drop rate of the conductive TFC-FO membrane reduced 10.1% and the foulants decreased 94.6%. The introduction of the CNTs intermediate layer effectively improves the performance of the FO membrane and alleviates the organic fouling with the help of the applied electric field.


Funds:
山东省重大科技创新工程项目(2018CXGC1006);江苏省“六大人才高峰”高层次人才项目(JNHB-014)

AuthorIntro:
徐梦思(1996-),女,河南驻马店人,硕士生,主要从事膜法水处理技术研究

Reference:

 [1]  胡群辉,邹昊,姜莹,等. 正渗透膜分离关键技术及其应用进展[J]. 膜科学与技术,2014345):109-115.

[2]  Shen LZhang XZuo Jet al. Performance enhancement of TFC FO membranes with polyethyleneimine modification and post-treatment[J]. J Membr Sci201753446-58.

[3]  Zhao SZou LTang C Yet al. Recent developments in forward osmosis: Opportunities and challenges[J]. J Membr Sci20123961-21.

[4]  范良千,罗鸿兵,陈凤辉. 正渗透技术在水处理和能源开发中的研究进展[J]. 膜科学与技术,2014344):120-127.

[5]  Chou SWang RShi Let al. Thin-film composite hollow fiber membranes for pressure retarded osmosis (PRO) process with high power density[J]. J Membr Sci201238925-33.

[6]  Werner C MLogan B ESaikaly P Eet al. Wastewater treatment, energy recovery and desalination using a forward osmosis membrane in an air-cathode microbial osmotic fuel cell[J]. J Membr Sci2013428116-122.

[7]  Hoover L APhillip W ATiraferri Aet al. Forward with Osmosis: Emerging Applications for Greater Sustainability[J]. Environ Sci Technol201145(23)9824-9830.

[8]  Ren JMccutcheon J R. A new commercial thin film composite membrane for forward osmosis[J]. Desalination2014343187-193.

[9]  薛念涛,潘涛. 正渗透浓差极化与膜污染特征的研究进展[J]. 膜科学与技术,2015355):109-113.

[10] Mccutcheon J RElimelech M. Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis[J]. J Membr Sci2006284(1-2)237-247.

[11] Tang M K YNg H Y. Impacts of different draw solutions on a novel anaerobic forward osmosis membrane bioreactor (AnFOMBR)[J]. Water Sci Technol201469(10)2036-2042.

[12] Chen LGu YCao Cet al. Performance of a submerged anaerobic membrane bioreactor with forward osmosis membrane for low-strength wastewater treatment[J]. Water Res201450114-123.

[13] 王涛,王宁,陆金仁,等. 正渗透膜污染特征及抗污染正渗透膜研究进展[J]. 膜科学与技术,2017371):125-132.

[14] Fan X FLiu Y MQuan Xet al. Highly Permeable Thin-Film Composite Forward Osmosis Membrane Based on Carbon Nanotube Hollow Fiber Scaffold with Electrically Enhanced Fouling Resistance[J]. Environ Sci Technol2018521444-1452.

[15] Liu YMi B. Combined fouling of forward osmosis membranes: Synergistic foulant interaction and direct observation of fouling layer formation[J]. J Membr Sci2012407-408136-144.

[16] 李玲,王新华,李秀芬,等. EDTA吸附材料控制厌氧正渗透膜生物反应器中正渗透膜的污染[J]. 膜科学与技术,2019394):82-88.

[17] Lin Y LTsai J ZHung C H. Using in situ modification to enhance organic fouling resistance and rejection of pharmaceutical and personal care products in a thin-film composite nanofiltration membrane[J]. Environ Sci Pollut Res201826(33)34073-34084.

[18] Gutierrez R SLopez R J AHassani Z Met al. Optimization of the Sequence of Washing Reverse Osmosis Membranes Used for Seawater Desalination[J]. Chem Biochem Eng Q201731(1)21-31.

[19] Wang X HHu T ZWang Z Wet al. Permeability recovery of fouled forward osmosis membranes by chemical cleaning during a long-term operation of anaerobic osmotic membrane bioreactors treating low-strength wastewater[J]. Water Res2017123(15)505-512.

[20] 张国俊,刘忠洲. 膜过程中膜清洗技术研究进展[J]. 水处理技术,2003,(4):187-190.

[21] Nayak VJyothi M SBalakrishna Geetha Ret al. 4-aminophenyl sulfone (APS) as novel monomer in fabricating paper based TFC composite for forward osmosis: Selective layer optimization[J]. J Environ Chem Eng20208(2)103664.

[22] Liu QQiu GZhou Zet al. An Effective Design of Electrically Conducting Thin-Film Composite (TFC) Membranes for Bio and Organic Fouling Control in Forward Osmosis (FO)[J]. Environ Sci Technol201650(19)10596-10605.

[23] 赵凤. 导电膜加电场减缓膜污染及电催化作用研究[D]. 大连:大连理工大学,2013.

[24] Wu M BLv YYang H Cet al. Thin film composite membranes combining carbon nanotube intermediate layer and microfiltration support for high nanofiltration performances[J]. J Membr Sci2016515238-244.

[25] Yuan BWang X HTang C Yet al. In situ observation of the growth of biofouling layer in osmotic membrane bioreactors by multiple fluorescence labeling and confocal laser scanning microscopy[J]. Water Res201575188-200.

[26] 周宗尧,胡云霞,李金强,等. 碳纳米管中间层高性能正渗透复合膜的制备与研究[J]. 膜科学与技术,2018383):34-4047.

[27] Zhou Z YHu Y XBoo Cet al. High-Performance Thin-Film Composite Membrane with an Ultrathin Spray-coated Carbon Nanotube Interlayer[J]. Environ Sci Technol Lett20185(5)243-248.


Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号