| 醋酸纤维素氨基甲酸酯膜材料的制备与表征 |
| 作者: 青岛科技大学化工学院,青岛 266042 |
| 单位: 青岛科技大学化工学院,青岛 266042 |
| 关键词: 醋酸纤维素;尿素;醋酸纤维素氨基甲酸酯;取代度;成膜性能 |
| DOI号: |
| 分类号: O636.1+1 |
| 出版年,卷(期):页码: 2013, 33(3):59-63 |
|
摘要: |
|
利用尿素对醋酸纤维素(CA)进行浸泡预处理,然后移入邻二甲苯惰性体系中进行反应。探讨合成过程中的影响因素,结果如下所示:预处理过程中尿素的浓度为25%,预处理温度55℃,预处理时间5h,反应时间3.5h时,所得醋酸纤维素氨基甲酸酯(CAC)取代度可达到0.1。FT-IR表征可以证明成功合成出了CAC。用制备的CAC进行铸膜,CAC膜的拉伸强度及水通量要优于CA膜,同时研究得出随着取代度的升高,CAC膜的拉伸强度及水通量呈上升趋势。 |
|
Using urea to cellulose acetate (CA) for soaking pretreatment, and then transfer CA into o-xylene inert system for reaction. These factors have been explored at the process of synthesis and the results were shown as follows: Pretreatment concentration was 25%, pretreatment temperature was 55 ℃, pretreatment time was 5 h, and the reaction time was 3.5 h. On this condition, the degree of substitution of CAC was able to be 0.1. FT-IR characterization proved that the CAC was successful synthetized. Use the CAC and CA for casting film, the tensile strength and water flux of CAC membrane is better than that of CA membrane. The study concluded that with the degree of substitution increases, CAC film tensile strength and water flux shows increase trend. |
|
基金项目: |
| 国家自然科学基金项目(No.21176131). |
|
作者简介: |
|
Using urea to cellulose acetate (CA) for soaking pretreatment, and then transfer CA into o-xylene inert system for reaction. These factors have been explored at the process of synthesis and the results were shown as follows: Pretreatment concentration was 25%, pretreatment temperature was 55 ℃, pretreatment time was 5 h, and the reaction time was 3.5 h. On this condition, the degree of substitution of CAC was able to be 0.1. FT-IR characterization proved that the CAC was successful synthetized. Use the CAC and CA for casting film, the tensile strength and water flux of CAC membrane is better than that of CA membrane. The study concluded that with the degree of substitution increases, CAC film tensile strength and water flux shows increase trend. |
|
参考文献: |
|
[1]叶代勇, 黄洪, 傅和青等. 纤维素化学研究进展. 化工学报, 2006, 57(8): 1782-1791. |
|
服务与反馈: |
| 【Download】【加入收藏】 |
《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-80492417/010-80485372 传真:010-80485372邮箱:mkxyjs@163.com
京公网安备11011302000819号