| 丙烯酸在阴离子交换膜中的传质特性研究 |
| 作者: 1.兰州交通大学环境与市政工程学院,兰州,700070;2.中国环境科学研究院水污染控制技术研究中心,北京,100012 |
| 单位: 1.兰州交通大学环境与市政工程学院,兰州,700070;2.中国环境科学研究院水污染控制技术研究中心,北京,100012 |
| 关键词: 双极膜电渗析;丙烯酸;阴离子交换膜;传质特性 |
| DOI号: |
| 分类号: TQ028 |
| 出版年,卷(期):页码: 2013, 33(5):38-42 |
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摘要: |
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本文研究了丙烯酸在两种不同阴离子交换膜(JAM-I-10和ACM均相膜)中的扩散特性。试验结果表明,温度和丙烯酸浓度对丙烯酸在JAM-I-10和ACM均相膜中传质的影响规律一致。在温度15~30℃之间,传质系数随温度的升高而增大,符合阿累尼乌斯方程。在温度20℃,酸室丙烯酸初始浓度为0.5~4.0mol/L条件下,传质系数随丙烯酸浓度变化不大;同等条件下,丙烯酸在ACM均相膜中的传质系数明显低于JAM-I-10均相膜。 |
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the mass transfer characteristics of the acrylic acid in two different anion exchange membranes (JAM-I-10 and ACM homogeneous membrane) were studied. It was indicated that the effect of temperature and acrylic acid concentration on mass transfer coefficient across JAM-I-10 and ACM membranes was the same. In the range of 15 to 30℃, the mass transfer coefficient increased with the increase of the temperature and followed the Arrhenius' Equation. At the temperature of 20℃, when the concentration of acrylic acid increased from 0.5mol/L to 4.0mol/L, the mass transfer coefficient changed little. Under the same condition, the mass transfer coefficient of acrylic acid in the ACM homogeneous membrane was significantly lower than that in the JAM-I-10 homogeneous membrane. |
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基金项目: |
| 基金项目:国家“水体污染控制与治理”科技重大专项(2012ZX07201-005) |
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作者简介: |
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the mass transfer characteristics of the acrylic acid in two different anion exchange membranes (JAM-I-10 and ACM homogeneous membrane) were studied. It was indicated that the effect of temperature and acrylic acid concentration on mass transfer coefficient across JAM-I-10 and ACM membranes was the same. In the range of 15 to 30℃, the mass transfer coefficient increased with the increase of the temperature and followed the Arrhenius' Equation. At the temperature of 20℃, when the concentration of acrylic acid increased from 0.5mol/L to 4.0mol/L, the mass transfer coefficient changed little. Under the same condition, the mass transfer coefficient of acrylic acid in the ACM homogeneous membrane was significantly lower than that in the JAM-I-10 homogeneous membrane. |
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参考文献: |
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[1] 张立岩,戴伟.丙烯氧化合成丙烯酸工艺及催化剂的研究进展[J].石油化工,2010,39(7):818-822. |
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