琥珀酸作为一种重要的C4平台化合物，可以直接用于表面活性剂、离子螯合剂等化学产品的制备，其30多种衍生物具有更为广阔的应用领域。鉴于双极膜电渗析能成功将琥珀酸钠转换成琥珀酸，对比研究了两种双极膜及两种离子交换膜提取琥珀酸的差异。研究结果表明，使用双极膜BPM-2时，琥珀酸回收率在90%以上，能耗在4kWh/kg以下，电流效率大于80%。此外，两种离子交换膜相比较，性能上没有太大差别。

Succinic acid, an important four-carbon dicarboxylic acid, is a key compound producing more than 30 commercially important productand can be used as surfactants and ion chelating agents. In this paper, we transformed sodium succinate into succinic acid bybipolar membrane electrodialysiswith different membranes. When the bipolar membraneBPM-2,succinic acid recovery was over 90%, energy consumption was less than 4 kWh/kg, current efficiency was more than 80%, which were better than those of domestic bipolar membrane. Through these comparisons, the difference of performances between heterogeneous exchange membranes and homogeneous ion exchange membranes was slightly.

[1] 王金主, 袁建国, 王元秀, 等. 发酵法生产琥珀酸的研究进展 [J]. 食品与药品, 2010,12(1):55-59.
[2] Song H, Huh YS, Lee SY, et al. Recovery of succinic acid produced by fermentation of a metabolically engineered Mannheimiasucciniciproducens strain [J]. Journal of biotechnology, 2007, 132:445-452.
[3] Chen Kequan, Zhang Han, MiaoYelian, et al. Succinic acid production from enzymatic hydrolysate of sake lees using Actinobacillussuccinogenes 130Z [J]. Enzyme and Microbial Technology, 2010,47: 236-240.
[4]OrjuelaA, J.YanezA, PeereboomL, et al. A novel process for recovery of fermentation-derived succinic acid [J]. Separation and Purification Technology, 2011,83:31-37.
[5] 付丽丽, 高学理, 范爱勇, 杨洋, 高从堦. 双极膜电渗析提取琥珀酸 [J]. 水处理技术. 2013, 39:35–38.
[6] 徐铜文. 离子交换膜的重大国家需求和创新研究 [J]. 膜科学与技术, 2008, 28(5):1-10.
[7] Choi J, Kim S, Moon S. Heterogeneity of Ion-Exchange Membranes: The Effects of Membrane Heterogeneity on Transport Properties [J]. Journal of Colloid and Interface Science,2001,241:120–126.
[8] Lee H, Hong M,Han S, et al. Influence of the heterogeneous structure on the electrochemical properties of anion exchange membranes [J]. Journal of Membrane Science, 2008, 320:549–555.
[9] StrathmannH.Electrodialysis, A mature technology with a multitude of new applications[J]. Desalination, 2010, 264:268–288.
[10]余翯, 徐铜文. 均相离子交换膜研究进展 [J]. 水处理技术, 2005,31(3) :1-4.
[11] 何炳林, 徐铜文, 李向华. 我国离子交换膜的生产与应用 [J]. 离子交换与吸附, 1998,14(1) :86-91.
[12]金可勇, 金水玉, 周勇,高从堦. BPM2型双极膜电渗析装置的研制[J]. 水处理技术, 2010, 36(2):119-125.
[13]ZhangKai, WangMeng, WangDuo,et al. The energy-saving production of tartaric acid using ion exchange resin-filling bipolar membrane electrodialysis[J]. Journal of Membrane Science, 2009,341:246-251.
[14]王振,等.离子交换膜制备、性能及应用[M]. 北京: 化学工业出版社, 1986:2-15.
[15] Wang Xinxin, WangMeng, JiaYuxiang, et al. The feasible study on the reclamation of the glyphosate neutralization liquor by bipolar membrane electrodialysis[J]. Desalination, 300 (2012) 58-63.