论文以煤粉为原料，经半干法压制成型、干燥、炭化等工艺制备出一种电催化膜材料-煤基板状微滤炭膜。考察了煤种的配比、粘结剂、造孔剂以及成型压力对煤基板状微滤炭膜孔性能的影响，并通过FT-IR、SEM、气体泡压法等对煤基板状微滤炭膜的结构性能进行表征。结果表明：改变混煤中焦煤的比例可以调控炭膜的孔结构；添加剂的加入有利于提高炭膜的孔结构性能，但在一定程度上降低了炭膜的机械性能及导电性；增大成型压力可改善炭膜的机械强度及导电性，对孔结构性能改变影响不大。

The coal-based flat microfiltration carbon membrane used for electrocatalytic membrane was prepared by the procedure of semi-dry pressing, drying and carbonization of carbonaceous precursor. Effects of the ratio of coking coal and lean coal, binder, pore-forming agents and briquetting pressure on the pore structure performance of the coal-based carbon membrane were investigated. Morphology and pore structure characteristics of carbon membrane were characterized by FT-IR, SEM and bubble-pressure method. The result shows that the pore structure of carbon membrane can be adjusted by controlling the ratio of coking coal and lean coal. Additive benefits the improvement of the pore structure performance of carbon membrane, but decreases the mechanical strength and electrical conductivity of carbon membrane. It is favorable to improve the mechanical strength and electrical conductivity of carbon membrane by increasing briquetting pressure, which has less influence on the pore structure properties of carbon membrane.

[1] 汪锰，王湛，李政雄.膜材料及其制备[M].北京：化学工业出版社，2003.
[2] 徐南平，邢卫红，赵宜江.无机膜分离技术与应用[M].北京：化学工业出版社，2003.
[3] Chen Xuejun，Shen Zhemin，Zhu Xiaolong，et al. Advanced treatment of textile wastewater
for reuse using electrochemical oxidation and membrane filtration[J].Water SA，2005，31（1）：127-132.
[4] 陈冬梅.炭膜研究新进展[J].化工生产与技术. 2011，18(5)：40-43.
[5] Sonny Sachdeva，Anil Kumar. Preparation of nonporous composite carbon membrane for separation of rhodamine B dye[J]. Journal of Membrane Science，2009，329：2-10.
[6] 宋成文，陶平，宋学凯等.煤基多孔炭膜去除压藻水中微藻的研究用作炭薄膜前驱体的[J].无机材料学报，2013，28(10)：1067-1071.
[7] Wall Y，Braun G，Kaltenborn N，etal. Separation of CO2/N2 by means of a carbon membrane[J]. Chemical Engineering&Technology.2012，35(3)：508-512.
[8] Salleh W，Ismail AF.Effects of carbonization heating rate on CO2 separation of derived carbon membranes[J]. Separation and Purification Technology，2012，88：174–183.
[9] Rungta M，Xu L，Koros W.Carbon molecular sieve dense film membranes derived from Matrimid® for ethylene/ethane separation[J].Carbon，2012，50(4)：1488–1502.
[10] Yang Yang，Jianxin Li，Hong Wang，et al. An Electro catalytic Membrane Reactor with Self-Cleaning Function for Industrial Wastewater Treatment [J].Angew Chem，2011，123：2196–2198.
[11] 宋学凯，王同华，张万栋等.煤基管状炭膜的增强改性[J].膜科学与技术，2011，31(1)：51-55.
[12] 王同华，宋成文.一种煤基炭膜的制备方法[P]：中国，发明专利，CN1490076.2004.04.21.
[13] 王同华，宋成文.一种煤基炭膜的调孔方法[P]：中国，发明专利，CN1490075.2004.04.2 1.
[14] 宋成文.煤基炭膜的制备、孔结构调控及应用[D].大连：大连理工大学2006.
[15] 李建新，王虹，杨阳. 膜技术处理印染废水研究进展[J].膜科学与技术，2011，31(3)： 145-148.
[16] 李建新，王同华，马军等. 一种抗污染电催化膜基反应器[P].国际，发明专利：申请号PCT/CN 2009/074542，2009-10-20.
[17] 张秀伟，王虹，杨阳等. 基于含油废水处理的电催化膜反应器优化设计及性能研究[J].膜科学与技术，2012，32(5)：20-25.