| 从海水中选择性提钾的双极膜的研制及其应用 |
| 作者: 1福建省农业科学院农业工程技术研究所,福建 福州 350003; |
| 单位: 1福建省农业科学院农业工程技术研究所,福建 福州 350003; |
| 关键词: 18–冠醚–6;离子印迹双极膜;制备;表征;应用 |
| DOI号: |
| 分类号: TQ443.3 |
| 出版年,卷(期):页码: 2015, 35(3):85-91 |
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摘要: |
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以羧甲基纤维素钠(CMC)和壳聚糖(CS)分别作为制备双极膜阳、阴极膜的天然材料,然后分别以18–冠醚–6(18–C–6)和戊二醛(GA)改性,采用流延法制备mCMC +18–C–6/mCS离子印迹双极膜。从含水率、红外、热稳定性、跨膜电压、交流阻抗等方面表征该离子印迹双极膜的性能。测定结果表明,改性后的离子印迹双极膜性能得到提高。并将改性后的离子印迹双极膜应用于宁德市海水中提取钾资源,当渗透时间为150min时,K+透过改性后的离子印迹双极膜的透过率最大,高达95%。 |
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Sodium carboxymethyl cellulose (CMC) and Chitosan (CS) were prepared as natural materials,then modified by 18–crown–6 (18–C–6) and glutaraldehyde (GA), respectively. mCMC+18–C–6/mCS ion imprinted bipolar membrane(IIBPM)was prepared by a paste method.The IIBPM was characterized by moisture content,Infrared Spectroscopy (IR), transmembrane voltage, AC impedance,thermal stability,respectively. The results showed that the property of IIBPM was improved after modified by 18–C–6.mCMC+18–C–6/mCS IIBPM was applied to extract potassium resources in Ningde city. When the penetration time was 150 min, the permeability rate of K+ through the mCMC+18–C–6/mCS IIBPM was up to 95%. |
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基金项目: |
| 福建省省属公益类优势领域项目(2014R1015-13);2014年度农科院院青年科技创新项目(2014CX-14、2014CX-13) |
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作者简介: |
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Sodium carboxymethyl cellulose (CMC) and Chitosan (CS) were prepared as natural materials,then modified by 18–crown–6 (18–C–6) and glutaraldehyde (GA), respectively. mCMC+18–C–6/mCS ion imprinted bipolar membrane(IIBPM)was prepared by a paste method.The IIBPM was characterized by moisture content,Infrared Spectroscopy (IR), transmembrane voltage, AC impedance,thermal stability,respectively. The results showed that the property of IIBPM was improved after modified by 18–C–6.mCMC+18–C–6/mCS IIBPM was applied to extract potassium resources in Ningde city. When the penetration time was 150 min, the permeability rate of K+ through the mCMC+18–C–6/mCS IIBPM was up to 95%. |
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参考文献: |
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[1] 徐铜文.离子交换膜的重大国家需求和创新研究[J].膜科学与技术,2008,28(5):1~10. |
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