本文针对以聚甲基丙烯酸甲酯为主要成分的退浆废水，采用孔径为50 nm的陶瓷膜过滤，实现废水的资源化利用。采用两级串联先循环后浓缩的操作方式。循环过滤时，拟稳态通量为423 L·m-2·h-1和453 L·m-2·h-1。循环结束后进行浓缩，浓缩倍数达到22倍时通量为66 L·m-2·h-1和54 L·m-2·h-1；膜对COD的截留率为87.5%，产水浊度低于1 NTU，废水中的氢氧化钠等小分子物质均透过膜层进入渗透液；膜污染是以聚甲基丙烯酸酯在膜表面形成滤饼为主；碱洗及酸洗膜通量恢复至新膜的95%以上。陶瓷膜出水回用于生产过程；工业化陶瓷膜运行稳定，经济效益显著。
 

In present paper, ceramic membrane with pore size of 50 nm was adopted to resource utilization the desizing wastewater, of which PMMA is the basis content. A two-stage series operation mode was employed, and the process was operated with recirculation and then concentration. The pseudo-steady fluxes of membranes in the first module and second module were 423 L•m-2•h-1and 453 L•m-2•h-1, respectively. Concentration operation was conducted after recirculation and, the fluxes of the two membranes were 66 L•m-2•h-1and 54 L•m-2•h-1 when the concentration ratio was 22. The membranes performed COD retention of 87.5% and the turbidity of the permeated water was lower than 1 NTU. No rejection was detected for the components with low molecular weight such as NaOH. It was found that the main membrane fouling was caused by the cake formation of PMMA on membrane surface, and the permeability recovered to be higher than 95%. The water produced by these ceramic membranes was reused to the production process, and the industrial scale membrane system run stably, economically showing good performance.
 

[1] 雷乐成, 光助Fenton 氧化处理PVA 退浆废水的研究, 环境科学学报, 2000, 2,139-144.
[2] 于奕峰, 顾春雷, 王广玉, 吕红涛, 张月萍, 袁中凯, 有机超滤膜处理退浆废水实验研究, 膜科学与技术, 2008,1,72-76.
[3] 王星骅, 柳林, 陈季华, 动态陶瓷膜对PVA退浆废水处理效果的研究, 科技情报开发与经济, 2008,18, 132-134.
[4] 范苏, 邱鸣慧, 周邢, 范益群, 多通道Ti02超滤膜的制备及其在印染废水中的应用, 南京工业大学学报(自然科学版), 2011, 33,44-47.
[5] 王峰, 王福利, 江中央, 傅美强, 陶瓷膜与盐析法组合工艺去除退浆废水中的PVA, 海峡科学, 2013,41-43.
[6] H. Zhang, Z. Zhong, W. Xing, Application of ceramic membranes in the treatment of oilfield-produced water: Effects of polyacrylamide and inorganic salts, Desalination, 2013, 309, 84-90.
[7] H. Zhang, Z. Zhong, W. Li, W. Xing, W. Jin, River Water Purification via a Coagulation-Porous Ceramic Membrane Hybrid Process, Chinese Journal of Chemical Engineering, 2014 ,22, 113—119.
[8] A.R. Costa, M.N. Pinho, M. Elimelech, Mechanisms of colloidal natural organic matter fouling in ultrafiltration, J. Membr. Sci., 2006,281, 716-725.
[9] 奚强, 李亮, 赵雷, 程时远, 反相微乳液模板原位聚合制备和表征纳米AgCl—PMMA 复合材料, 高分子材料科学与工程, 2003, 19,213-216.