为制备高通量α-Al2O3陶瓷超滤膜，本文采用改进的溶胶凝胶法，通过在勃姆石溶胶中添加TiO2促进Al2O3膜材料在相对较低的温度下由γ相向α相转变，改变了γ-Al2O3的片层结构，减小了曲折因子。基于溶质截留法，分析了TiO2的添加对膜材料孔径分布的影响。虽然TiO2的添加使得平均孔径有所增加，但提升了孔径分布的均一性。此外，TiO2的添加还提升了膜材料的亲水性。在几方面的综合作用下，制备出高通量的α-Al2O3超滤膜，其平均孔径约为8.2 nm，纯水渗透率约为2300 L/(m2·h·MPa)。与未添加TiO2制备的超滤膜相比，其纯水渗透率提高了65 %左右，但对葡聚糖的截留性能变化不大，截留分子量约为30.0 kDa。

 To prepare high-flux α-Al2O3 ceramic ultrafiltration membranes, an improved sol-gel method was used in this paper to promote the transition of the alumina membrane material from γ-phase to α-phase at relatively low temperatures by adding titania to the boehmite sol-gel. The lamellar structure of γ-Al2O3 was changed, and the corresponding tortuosity factor was reduced. Based on the solute rejection method, the effect of titania addition on the pore size distribution was analyzed. Although, the addition of titania resulted in an increase in the average pore size, it enhanced the homogeneity of the pore size distribution. In addition, titanium oxide enhanced the hydrophilicity of the membrane material. Finally, a high-flux α-Al2O3 ultrafiltration membrane with an average pore size of about 8.2 nm and a pure water permeability of about 2300 L/(m2·h·MPa) was obtained. Compared to the ultrafiltration membrane obtained without the addition of titania, the permeability of the pure water was increased by about 65%, while the retention of dextran did not change much. The MWCO was kept at the original level of about 30.0 kDa.

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