| PP/POE中空纤维膜的制备及其VMD应用研究 |
| 作者: 天津科技大学化工与材料学院,天津,300457 |
| 单位: 天津科技大学化工与材料学院,天津,300457 |
| 关键词: 中空纤维膜;聚丙烯;POE含量;热致相分离;真空膜蒸馏 |
| DOI号: |
| 分类号: TQ028.8 |
| 出版年,卷(期):页码: 2021, 41(1):89-94 |
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摘要: |
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选用乙烯-辛烯共聚物(POE)作为聚丙烯(PP)共混增韧改性材料,通过热致相分离法制备PP/POE中空纤维膜,研究POE含量对膜性能的影响。结果表明:POE最佳添加量为15%,共混膜的水接触角提高8.5%,平均孔径提高24.83%,真空膜蒸馏(VMD)通量从8.36 kg·m-2·h-1增加到12.60 kg·m-2·h-1,提高了50.72%;膜的拉伸强度提高了12.82%,最大伸长率提高了51.89%。 |
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This study selected ethylene-octene copolymer (POE) as polypropylene (PP) blend toughening modified material to prepare PP/POE hollow fiber membrane by thermally induced phase separation to study the effect of POE content on membrane properties. The results showed that the optimal addition of POE was 15%, the water contact angle of the blend membrane was increased by 8.5%, the average pore size was increased by 24.83%, and the flux of vacuum membrane distillation (VMD) increased from 8.36 kg·m-2·h-1 to 12.60 kg·m-2·h-1, an increase of 50.72%; the tensile strength of the membrane increased by 12.82%, and the maximum elongation increased by 51.89%. In this work, ethylene-octene copolymer (POE) was used as toughening modification material to prepare PP/POE co-blend hollow fiber membrane by thermally induced phase separation. The effect of POE content on membrane properties and performance was investigated. Under optimum condition ( 15%(wt) POE ), the water contact angle, the average pore size, the flux, the tensile strength, and elongation were improved 8.5%, 24.83%, 50.72%, 12.82%, and 51.89%, respectively. The flux of vacuum membrane distillation (VMD) increased from 8.36 kg·m-2·h-1 to 12.60 kg·m-2·h-1. |
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基金项目: |
| 天津市自然科学基金(18JCZDJC37200);天津市自然基金(17JCQNJC13200);天津市海洋资源与化学重点实验室项目(201404);教育部创新团队发展计划项目(IRT-17R81) |
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作者简介: |
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This study selected ethylene-octene copolymer (POE) as polypropylene (PP) blend toughening modified material to prepare PP/POE hollow fiber membrane by thermally induced phase separation to study the effect of POE content on membrane properties. The results showed that the optimal addition of POE was 15%, the water contact angle of the blend membrane was increased by 8.5%, the average pore size was increased by 24.83%, and the flux of vacuum membrane distillation (VMD) increased from 8.36 kg·m-2·h-1 to 12.60 kg·m-2·h-1, an increase of 50.72%; the tensile strength of the membrane increased by 12.82%, and the maximum elongation increased by 51.89%. In this work, ethylene-octene copolymer (POE) was used as toughening modification material to prepare PP/POE co-blend hollow fiber membrane by thermally induced phase separation. The effect of POE content on membrane properties and performance was investigated. Under optimum condition ( 15%(wt) POE ), the water contact angle, the average pore size, the flux, the tensile strength, and elongation were improved 8.5%, 24.83%, 50.72%, 12.82%, and 51.89%, respectively. The flux of vacuum membrane distillation (VMD) increased from 8.36 kg·m-2·h-1 to 12.60 kg·m-2·h-1. |
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参考文献: |
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[1]罗本喆.热致相分离法制备聚丙烯微孔膜的研究[D].江苏:南京工业大学,2005. |
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