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碳点在膜技术中的应用进展

作者： 1.哈尔滨工业大学（威海）海洋科学与技术学院，山东 264209；2.哈尔滨工业大学（威海）中欧膜技术研究院，山东 264209

单位： 1.哈尔滨工业大学（威海）海洋科学与技术学院，山东 264209；2.哈尔滨工业大学（威海）中欧膜技术研究院，山东 264209

关键词：碳点；复合膜；膜分离；气体分离；水处理；有机溶剂分离

DOI号：

分类号： O631；TB324；TQ316.6

出版年,卷(期):页码： 2023, 43(4):196-204

摘要：

?碳点 (CDs) 是一种新型的零维碳基材料。CDs具有超小尺寸、亲水性强、丰富的表面官能团、易于合成和良好的水溶性等优异特性。通过调控CDs的性质可以提高复合膜的水通量和分离性能，将其引入膜材料中对开发高渗透性和高选择性复合膜具有重要意义。因此，CDs在膜分离领域展现了巨大的应用前景。本文介绍了CDs或改性CDs的合成方法，总结了CDs复合膜的制备及其在气体分离、水净化、有机溶剂分离等领域的应用。最后，对CDs在膜技术领域的应用中所面临的机遇与挑战进行展望。

Carbon Dots (CDs) are a fascinating class of zero-dimensional carbon-based nanomaterials. CDs have excellent structural and physicochemical properties, such as ultra-small size, tunable hydrophilicity, abundant surface functional groups, good water solubility and straightforward synthesis method. Introducing CDs with controllable properties enhances the water permeance and molecular sieving of the polymeric membranes, which is of vital importance to composite membrane for separation processes. Therefore, CDs have attracted great attention in the field of membrane technology. This review summarizes the synthesis methods of CDs and the preparation of CDs composite membranes. The discussion focuses on the application of CDs composite membranes in the fields of gas separation, water purification and organic solvent separation. Finally, we propose the future opportunities and challenges faced by CDs in the field of membrane technology.

基金项目：

哈尔滨工业大学（威海）青年教师发展基金（理工类）(IDGA10002136)

作者简介：

参考文献：

[1] Tawalbeh M, Al Mojjly A, Al-Othman A, et al. Membrane separation as a pre-treatment process for oily saline water[J]. Desalination, 2018, 447: 182-202.

[2] Elimelech M, Phillip W A. The future of seawater desalination: energy, technology, and the environment[J]. Science, 2011, 333(6043): 712-7.

[3] Kosinov N, Gascon J, Kapteijn F, et al. Recent developments in zeolite membranes for gas separation[J]. J Membr Sci, 2016, 499: 65-79.

[4] Zhao D L, Japip S S, Zhang Y, et al. Emerging thin-film nanocomposite (TFN) membranes for reverse osmosis: A review[J]. Water Res, 2020, 173: 115557.

[5] Liu F, Jang M H, Ha H D, et al. Facile synthetic method for pristine graphene quantum dots and graphene oxide quantum dots: origin of blue and green luminescence[J]. Adv Mater, 2013, 25(27): 3657-62.

[6] Demchenko A P, Dekaliuk M O. Novel fluorescent carbonic nanomaterials for sensing and imaging[J]. Methods Appl Fluoresc, 2013, 1(4): 042001.

[7] Liu J J, Li R, Yang B. Carbon Dots: A New Type of Carbon-Based Nanomaterial with Wide Applications[J]. ACS Cent Sci, 2020, 6(12): 2179-95.

[8] Long C C, Jiang Z X, Shangguan J F, et al. Applications of carbon dots in environmental pollution control: A review[J]. Chem Eng J, 2021, 406.

[9] Fernando K A, Sahu S, Liu Y M, et al. Carbon quantum dots and applications in photocatalytic energy conversion[J]. ACS Appl Mater Interfaces, 2015, 7(16): 8363-76.

[10] Dong Y Q, Wang R X, Li H, et al. Polyamine-functionalized carbon quantum dots for chemical sensing[J]. Carbon, 2012, 50(8): 2810-5.

[11] Luo P G, Sahu S, Yang S T, et al. Carbon “quantum” dots for optical bioimaging[J]. J Mater Chem B, 2013, 1(16): 2116-27.

[12] ?oczechin A, Séron K, Barras A, et al. Functional carbon quantum dots as medical countermeasures to human coronavirus[J]. ACS Appl Mater Interfaces, 2019, 11(46): 42964-74.

[13] Shen L M, Liu J. New development in carbon quantum dots technical applications[J]. Talanta, 2016, 156-157: 245-56.

[14] Xu X Y, Ray R, Gu Y L, et al. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J]. J Am Chem Soc, 2004, 126(40): 12736-7.

[15] Sun Y P, Zhou B, Lin Y, et al. Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence[J]. J Am Chem Soc, 2006, 128(24): 7756-7.

[16] Shen J H, Zhu Y H, Yang X L, et al. One-Pot Hydrothermal Synthesis of Graphene Quantum Dots Surface-Passivated by Polyethylene Glycol and Their Photoelectric Conversion under Near-Infrared Light[J]. New J Chem, 2011, 36: 97-101.

[17] Dong Y Q, Shao J W, Chen C Q, et al. Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid[J]. Carbon, 2012, 50(12): 4738-43.

[18] Monje D S, Chacon K M, Galindo I C, et al. Carbon dots from agroindustrial residues: a critical comparison of the effect of physicochemical properties on their performance as photocatalyst and emulsion stabilizer[J]. Mater Today Chem, 2021, 20: 100445.

[19] Zhao D L, Japip S, Zhang Y, et al. Emerging thin-film nanocomposite (TFN) membranes for reverse osmosis: A review[J]. Water Res, 2020, 173: 115557.

[20] Li Y, Li S, Zhang K S. Influence of hydrophilic carbon dots on polyamide thin film nanocomposite reverse osmosis membranes[J]. J Membr Sci, 2017, 537: 42-53.

[21] Yang C, Li Y, Long M Y, et al. Ultrathin nanofiltration membrane assembled by polyethyleneimine-grafted graphene quantum dots[J]. J Membr Sci, 2022, 642: 119944.

[22] Vatanpour V, Mousavi Khadem S S, Masteri-Farahani M, et al. Anti-fouling and permeable polyvinyl chloride nanofiltration membranes embedded by hydrophilic graphene quantum dots for dye wastewater treatment[J]. J Water Process Eng, 2020, 38: 101652.

[23] Koulivand H, Shahbazi A, Vatanpour V, et al. Development of carbon dot-modified polyethersulfone membranes for enhancement of nanofiltration, permeation and antifouling performance[J]. Sep Purif Technol, 2020, 230.

[24] Zhang B J, Wang W Y, Zhu L Y, et al. Simultaneously enhanced permeability and anti-fouling performance of polyethersulfone ultrafiltration membranes by structural control and mixed carbon quantum dots[J]. J Membr Sci, 2022, 641.

[25] Jafari A, Kebria M R S, Rahimpour A, et al. Graphene quantum dots modified polyvinylidenefluride (PVDF) nanofibrous membranes with enhanced performance for air Gap membrane distillation[J]. Chem Eng Process, 2018, 6(2): 117-24.

[26] Gu Q L, Ng T C A, Zain I, et al. Chemical-grafting of graphene oxide quantum dots (GOQDs) onto ceramic microfiltration membranes for enhanced water permeability and anti-organic fouling potential[J]. Appl Surf Sci, 2020, 502: 144128.

[27] Zhao D L, Das S, Chung T S. Carbon Quantum Dots Grafted Antifouling Membranes for Osmotic Power Generation via Pressure-Retarded Osmosis Process[J]. Environ Sci Technol, 2017, 51(23): 14016-23.

[28] Zeng Z P, Yu D S, He Z M, et al. Graphene Oxide Quantum Dots Covalently Functionalized PVDF Membrane with Significantly-Enhanced Bactericidal and Antibiofouling Performances[J]. Sci rep, 2016, 6: 20142.

[29] Niu Y H, Chen Y H, Bao S S, et al. Fabrication of polyarylate thin-film nanocomposite membrane based on graphene quantum dots interlayer for enhanced gas separation performance[J]. Sep Purif Technol, 2022, 293: 121035.

[30] Zhu Y, Zhang X J, Zhang L M, et al. Membranes constructed with zero-dimension carbon quantum dots for CO2 separation[J]. J Membr Sci, 2022, 664: 121086.

[31] Dou H Z, Xu M, Wang B Y, et al. Analogous mixed matrix membranes with self‐assembled interface pathways[J]. Angew Chem Int Ed, 2021, 60(11): 5864-70.

[32] Liu H L, Cheng S Y, Qin Y, et al. Engineering of macroscale graphene oxide quantum dots skeleton membrane via electrostatic spraying method[J]. J Membr Sci, 2022, 650: 120428.

[33] Song Y F, Sun Y K, Zhang N, et al. Custom-tailoring loose nanocomposite membrane incorporated bipiperidine/graphene quantum dots for high-efficient dye/salt fractionation in hairwork dyeing effluent[J]. Sep Purif Technol, 2021, 271: 118870.

[34] Liu Y, Qin Z P, Zhang X H, et al. In-situ growth of graphene quantum dots modified MoS2 membrane on tubular ceramic substrate with high permeability for both water and organic solvent[J]. J Membr Sci, 2021, 627: 119247.

[35] Lin Y Q, Shen Q, Kawabata Y, et al. Graphene quantum dots (GQDs)-assembled membranes with intrinsic functionalized nanochannels for high-performance nanofiltration[J]. Chem Eng J, 2021, 420: 127602.

[36] Gai W X, Zhang Y, Zhao Q P, et al. Highly permeable thin film composite hollow fiber membranes for brackish water desalination by incorporating amino functionalized carbon quantum dots and hypochlorite treatment[J]. J Membr Sci, 2021, 620: 118952.

[37] Yu T, Wang X, Liu Z Y, et al. Structure-performance relationships between amino acid-functionalized graphene quantum dots and self-cleaning nanofiltration membranes[J]. J Membr Sci, 2022, 644: 120068.

[38] Sun J W, Jia W, Guo J X, et al. Amino-embedded carbon quantum dots incorporated thin-film nanocomposite membrane for desalination by pervaporation[J]. Desalination, 2022, 533: 115742.

[39] Jain H, Kumar A, Rajput V D, et al. Fabrication and characterization of high-performance forward-osmosis membrane by introducing manganese oxide incited graphene quantum dots[J]. J Environ Manage, 2022, 305: 114335.

[40] Zainal Abidin N H, Shafie S N A, Suhaimi H, et al. Incorporation of carboxyl and amino functionalized carbon quantum dots in thin film membrane for nanofiltration[J]. Polym Test, 2021, 100: 107270.

[41] 袁佳彬. 碳量子点改性聚酰胺纳滤膜的制备及对稀土富集的研究[D]. 江西: 江西理工大学, 2020.

[42] Zahmatkesh S, Ni B J, Klemeš J J, et al. Carbon quantum dots-Ag nanoparticle membrane for preventing emerging contaminants in oil produced water[J]. J Water Process Eng, 2022, 50: 103309.

[43] Asadi Tashvigh A, Feng Y N, Weber M, et al. 110th Anniversary: Selection of Cross-Linkers and Cross-Linking Procedures for the Fabrication of Solvent-Resistant Nanofiltration Membranes: A Review[J]. Ind Eng Chem Res, 2019, 58(25): 10678-91.

[44] Fu W M, Zhang W, Chen H N, et al. A high-flux organic solvent nanofiltration membrane with binaphthol-based rigid-flexible microporous structures[J]. J Mater Chem A, 2021, 9(11).

[45] Yuan Z J, Wu X L, Jiang Y J, et al. Carbon dots-incorporated composite membrane towards enhanced organic solvent nanofiltration performance[J]. J Membr Sci, 2018, 549: 1-11.

[46] Li S X, Li C, Su B W, et al. Amino-functionalized graphene quantum dots (aGQDs)-embedded thin film nanocomposites for solvent resistant nanofiltration (SRNF) membranes based on covalence interactions[J]. J Membr Sci, 2019, 588: 117212.

[47] Lecaros R L G, Matira A R, Tayo L L, et al. Homostructured graphene oxide-graphene quantum dots nanocomposite-based membranes with tunable interlayer spacing for the purification of butanol[J]. Sep Purif Technol, 2022, 283: 120166.

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