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耐酸/碱有机纳滤膜研究进展及其应用

作者：赵亚丽，张严川，刘雨*

单位：南开大学低碳非常规水源资源化与水质保障平台环境科学与工程学院，天津 300350

关键词：纳滤膜；耐酸/碱；废液资源化；膜材料；膜制备

DOI号： 10.16159/j.cnki.issn1007-8924.2025.03.022

分类号： TQ028.8

出版年,卷(期):页码： 2025, 45(3):209-220

摘要：

纳滤（NF）膜因其优异的选择分离性能在废液资源化利用领域发挥着重要作用。然而，主流的聚酰胺NF膜存在极端pH值条件下耐受性不足的缺陷，而现有商品化的特种耐酸/碱有机NF膜在分离性能方面难以与聚酰胺NF膜相媲美，这严重制约了NF技术在废液资源化领域的应用。因此，开发新型高性能耐酸/碱有机NF膜对于满足工业分离需求、构建绿色循环经济体系具有重要的现实意义。本文以商品化耐酸/碱有机NF膜为研究对象，系统阐述了其材料组成、pH值适用范围、分离性能及现存挑战，重点综述了耐酸/碱有机膜材料及其制备方法的研究进展，并详细探讨了耐酸/碱有机NF膜的应用领域，以期为高性能耐酸/碱有机NF膜的开发及其在废液资源化中的应用提供理论指导和技术参考。

Nanofiltration (NF) membranes play a pivotal role in the resource recovery of waste liquids due to their superior selective separation properties. However, the widely used polyamide-based NF membranes exhibit poor resistance to extreme pH conditions, while commercially available acid/alkali-resistant NF membranes fail to match the separation performance of polyamide-based membranes. This limitation hinders the broader application of NF technology in waste liquid resource recovery. Developing novel high-performance acid/alkali-resistant NF membranes is of significant importance for meeting industrial separation requirements and advancing the construction of a green, circular economy. This paper focuses on commercially available acid/alkali-resistant organic NF membranes, providing a concise overview of their materials, pH tolerance range, separation performance, and the challenges they currently face. A comprehensive review of acid/alkali-resistant organic membrane materials and fabrication methods is presented, followed by an in-depth discussion of the application fields of acid/alkali-resistant NF membranes. The paper aims to provide valuable insights for developing high-performance acid/alkali-resistant organic NF membranes and their application in the resource recovery of waste liquids.

基金项目：

国家自然科学基金青年项目（52403134）; 中央高校基本科研业务费专项资金资助（040-63233182）

作者简介：

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